Isoreticular Chiral Metal−Organic Frameworks for... - Ahamed

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Isoreticular Chiral Metal−Organic Frameworks for Asymmetric Alkene Epoxidation: Tuning Catalytic Activity by Controlling Framework Catenation and Varying Open Channel Sizes, JACS, http://pubs.acs.org/doi...

October 24, 2010 - Comment - Like - Share

Matthew Todd liked this

Modified Jacobsen's Mn-salen with different linker length and Zn chelation. Changing the linker length changes the porosity and also increases rate and enantioselectivity of epoxidation. Why do they modified Jacobsen's Mn-salen with an additional metal and chelation to get a less effecient catalyst reaction with less stereochemical output? Recyclibility? Who cares..... - Ahamed

Micheal this one is for you....... - Ahamed

Thanks! - Michael Wolfle