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Trapping of picolyl cations in the reactions of 2- and 4-picoline N-oxide with acetic anhydride - Journal of the American Chemical Society (ACS Publications) - http://pubs.acs.org/doi...
Paper describing the use of anisole to probe the polar (ortho/para) or radical (meta) nature of a bond forming event. Relevant to Soo/Althea
- Matthew Todd
from Bookmarklet
Fwd: Short communication: Online lab books for supervision of project students - http://www.bioscience.heacademy.ac.uk/journal... (via http://friendfeed.com/jobadge...) (via http://friendfeed.com/the-lif...)
Ryan check this out
- Matthew Todd
USA to Australia Fellowship Applications - American Australian Association, Education - http://www.americanaustralian.org/usa%5Ft...
One-year grant for US graduate students to study in Aus
- Matthew Todd
from Bookmarklet
SpringerLink - Journal Article Bifunctional catalysis of Morita-Baylis-Hillman (MBH) reaction with chiral primary-tertiary diamine: - http://www.springerlink.com/content...
Ahamed, Althea - primary-tertiary amine catalysis
- Matthew Todd
from Bookmarklet
Iron-Catalyzed Selective Oxidation of N-Methyl Amines: Highly Efficient Synthesis of Methylene-Bridged bis-1,3-Dicarbonyl Compounds - Organic Letters (ACS Publications) - http://pubs.acs.org/doi...
Khalid Mirza and Jean-Claude Bradley liked this
New paper from Zhiping Li - nice iron-catalysed oxidation of CH next to N, here with an interesting cleavage of the N-C bond in the process. Althea, Soo.
- Matthew Todd
from Bookmarklet
Simple Cyclohexanediamine-Derived Primary Amine Thiourea Catalyzed Highly Enantioselective Conjugate Addition of Nitroalkanes to Enones - Organic Letters (ACS Publications) - http://pubs.acs.org/doi...
Ahamed, Nilupa - interesting use of nitroalkanes. Read and absorb.
- Matthew Todd
from Bookmarklet
Specificity in the interaction of non intercalative groove binding ligands with nucleic acids http://www.ias.ac.in/jarch...
One of my MOBT students alerted me to this study that casts doubt on the role of H-bonding in the AT-specificity of netropsin/distamycin binding. It's 25 years old now, but interesting.
- Matthew Todd
Japp–Klingemann reaction - Wikipedia, the free encyclopedia - http://en.wikipedia.org/wiki...
Nilupa - as it says - intermediate in Fischer indole synthesis
- Matthew Todd
from Bookmarklet
If anyone is looking to buy peptide coupling reagents, do check more widely than Sigma Aldrich - e.g. Advanced Chemtech :"RC8110 HATU 100g US$550, RC8116 HCTU 100g US$225, RC8106 HBTU 100g US$90" according to an email they keep sending. Alternatively try Ahamed's super method that obviates the need for them altogether.
Ahamed liked this
Know where these things are located around campus? Rutledge - wonder if we can use these? http://www.facebook.com/album...
Highly efficient cross-dehydrogenative-coupling between ethers and active methylene compounds - http://10.1002/anie.200503255
TotallySynthetic.com » Blog Archive » Haplophytine - http://totallysynthetic.com/blog...
Some interesting steps in this Fukuyama synthesis, especially the Friedel-Crafts and the enamide epoxidation (Ahamed). Check out the lactonisation final step. Oxidation of CH next to nitrogen using potassium ferricyanide. That's very nice, and surprisingly selective.
- Matthew Todd
from Bookmarklet
Intresting, i got a similar ring opening (rearrangement) with mCPBA on electron rich PZQ enamide ; proved by X-ray crystal structure. Waiting to get it published.
- Ahamed
:) We can publish it when you finish it...
- Matthew Todd
pHLIP-Mediated Translocation of Membrane-Impermeable Molecules into Cells - http://dx.doi.org/10...
Nice work by a friend of mine looking at membrane translocation by pHLIP proteins. Any of us want to get things into cells?
- Matthew Todd
Fwd: How to choose a good scientific problem | BenchFly Blog - http://www.benchfly.com/blog... (via http://friendfeed.com/shwu...)
A Novel Prins Cyclization through Benzylic/Allylic C−H Activation - http://dx.doi.org/10...
Synthetic Approach to Diterpene Alkaloids : Construction of the Bridged Azabicyclic Ring System of Kobusine - http://www.journalarchive.jst.go.jp/english...
Trapping of picolyl cations in the reactions of 2- and 4-picoline N-oxide with acetic anhydride - http://dx.doi.org/10...
Total Synthesis of (+)-Lyconadin A and Related Compounds via Oxidative C−N Bond Formation - http://dx.doi.org/10...
THE CHEMISTRY OF ORGANIC GOLD COMPOUNDS. III. DIRECT INTRODUCTION OF GOLD INTO THE AROMATIC NUCLEUS (PRELIMINARY COMMUNICATION) - Journal of the American Chemical Society (ACS Publications) - http://dx.doi.org/10...
Endeavour Awards for Australian applicants - http://www.endeavour.deewr.gov.au/Austral...
$ for 4-6 month stays in Asia-Pacific for Aus postgrad students - if there's a lab in a participating country you're interested in, this is the way to access some funding.
- Matthew Todd
from Bookmarklet
Changing the local coordination environment in mono- and bi- nuclear lanthanide complexes through “click” chemistry - http://dx.doi.org/10...
One for all the cyclamers to read.
- Matthew Todd
Foaming! « Org Prep Daily - http://orgprepdaily.wordpress.com/2009...
Extraordinarily diverse set of useful practical recommendations from Org Prep Daily. Well worth a scan.
- Matthew Todd
from Bookmarklet
liquidcarbon: Digging Chemdraw. - http://liquidcarbon.livejournal.com/29611...
Advice on Chemdraw hotkeys etc
- Matthew Todd
from Bookmarklet
PhD studentship in Organic Chemistry available in my lab at Sydney. See http://docs.google.com/View.... Permanent residents of Aus only, sorry.
Mike Chelen and Jean-Claude Bradley liked this
Postdoctoral Fellowship in Organic Synthesis available in my group at Sydney. See http://docs.google.com/View... for details.
Oxidative Carbocation Formation in Macrocycles: Synthesis of the Neopeltolide Macrocycle - http://dx.doi.org/10...
Diastereoselective Tetrahydropyrone Synthesis through Transition-Metal-Free Oxidative Carbon–Hydrogen Bond Activation - http://dx.doi.org/10...
Brønsted-Acid-Catalyzed Activation of Nitroalkanes: A Direct Enantioselective Aza-Henry Reaction - http://dx.doi.org/10...
Instantaneous SmI2/H2O/amine mediated reduction of nitroalkanes and α,β-unsaturated nitroalkenes - http://dx.doi.org/10...
Aza-Henry Reaction of Ketoimines Catalyzed by Na2CO3: An Efficient Way to β-Nitroamines - http://dx.doi.org/10...
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